Corrosion Behavior and Mechanism of Weld Joints of Q370qENH Weathering Steel After Submerged Arc Welding
SUN Hongbin1, YANG Shaojun1, ZHANG Cong2, YU Xiayang3, ZHU Zhihui4, WANG Bingfeng3
1.Shandong Railway Investment Holding Group Co Ltd, Jinan 250102, Shandong, China;
2.Qingdao Branch of China Railway №10 Engineering Group Co Ltd, Qingdao 266000, Shandong, China;
3.School of Materials Science and Engineering, Central South University, Changsha 410083, Hunan, China;
4.School of Civil Engineering, Central South University, Changsha 410075, Hunan, China
Abstract:In order to study the corrosion mechanism of welded material of Q370qENH weathering steel by submerged arc welding (SAW) , experiments were conducted on immersion corrosion and electrochemical corrosion of Q370qENH substrate samples and weld seam samples after SAW process, and the morphology and composition of the surface rust formed after immersion corrosion were characterized. The results indicate that the corrosion resistance of the weld seam of Q370qENH by SAW process is lower than the substrate, and its electrochemical impedance is 38% of the substrate. The reason for the lower corrosion resistance of weld seam than the substrate and the formation mechanism of surface rust were all analyzed. The research results can provide scientific and theoretical basis for the safety assessment for the service of weathering steel in engineering projects of steel bridges for high-speed railway, as well as its following maintenance.
孙洪斌, 杨少军, 张丛, 于夏洋, 朱志辉, 汪冰峰. 耐候钢Q370qENH埋弧焊焊接接头锈蚀行为与机理研究[J]. 矿冶工程, 2024, 44(1): 152-156.
SUN Hongbin, YANG Shaojun, ZHANG Cong, YU Xiayang, ZHU Zhihui, WANG Bingfeng. Corrosion Behavior and Mechanism of Weld Joints of Q370qENH Weathering Steel After Submerged Arc Welding. Mining and Metallurgical Engineering, 2024, 44(1): 152-156.
[1] 封 辉,刘 峰,王本贤,等. Cu和Cr对耐候钢的力学性能及耐蚀性能的影响[J]. 材料热处理学报, 2012,33(1):110-116.
[2] 张 兴,杜双明,张 伟,等. 特厚F690海工钢焊接接头的组织及腐蚀磨损研究[J]. 矿冶工程, 2019,39(5):111-113.
[3] 胡加瑞,刘 旺,谢 亿,等. 末级过热器12Cr2MoWVTiB/TP347H异种钢焊口失效分析[J]. 矿冶工程, 2015,35(1):123-125.
[4] Sakashita M, Sato N. The effect of molybdate anion on the ion-selectivity of hydrous ferric oxide films in chloride solutions[J]. Corrosion Science, 1977,17(6):473-486.
[5] FU G, GAO X, JIN D, et al. Effect of Mo, Cr on corrosion behavior of low-carbon weathering steels[C]//2012 AIST Steel Properties & Applications Conference Proceedings. 2012:509-515.
[6] Morcillo M, Díaz I, Chico B, et al. Weathering steels: from empirical development to scientific design. A review[J]. Corrosion Science, 2014,83(7):6-31.
[7] MA Y, LI Y, WANG F. Corrosion of low carbon steel in atmospheric environments of different chloride content[J]. Corrosion Science, 2009,51(5):997-1006.
[8] Kamimura T, Nasu S, Segi T, et al. Influence of cations and anions on the formation of β-FeOOH[J]. Corrosion Science, 2005,47(10):2531-2542.
[9] 宋立英. 紫外辐射对Q235碳钢/09CuPCrNi 耐候钢大气腐蚀过程影响机制的研究[D]. 青岛:中国科学院研究生院, 2015.