In combination with experiments and multi-step finite element simulation, the residual stress distribution in components manufactured by laser powder bed fusion (LPBF) and the influence of the initial residual stress field on the laser shock peening (LSP)-induced compressive residual stress field. The validity of the simulation results was verified by the residual stress values measured with X-ray diffraction. The results show that the thermal stress of the lower and middle layer materials in the component fabricated by LPBF undergoes a transition from zero stress, compressive stress, tensile stress to compressive stress, while the top layer material shows a transition from zero stress, compressive stress to tensile stress, thus leading to tensile residual stress occurred on the surface layer of LPBF fabricated component, while compressive residual stress in the lower part. The action of initial residual stress field results in the reduced peak value but increased depth of LSP-induced compressive residual stress. The initial residual tensile stress field of LPBF components can exert a suppressive and dragging effect on the reverse plastic deformation caused by surface waves, leading to reduced intensity and changed position of the “residual stress hole”, which can improve the uniformity of LSP-induced residual stress distribution.

To investigate the rheological properties of heat-treatment-free AlSi9MnMg alloy specifically for high-pressure die casting (HPDC) process, influence of temperature and shear rate on the viscosity of molten alloy was studied by using a rotational rheometer based on the Searle principle, and the microstructure of the samples in rheological testing was analyzed. The results indicate that the viscosity of molten alloy decreases as the temperature rises in the test. At a given temperature, the viscosity decreases as the shear rate increases. With the shear rate exceeding 800 s^-1, the viscosity remains unchanged with shear time at the same shear rate. Under the action of shear force, the dendritic grains in the melt undergo fragmentation, agglomeration and spheroidization. Moreover, as the temperature rises in the test, the particle agglomerates become smaller in size.

Based on the Derwent Innovations Index (DII), the technologies for recycling cathode materials in spent lithium-ion batteries were analyzed in terms of patent indicators, including the number of patent applications and patent holders, the number of priority rights in countries/regions, patent citations, patent H-index among others. It is found that the recycling technologies are in rapid development, and the Chinese research organizations have created a patent portfolio plan, including a large number of high-quality patents that can improve competition. Over the past five years, the technologies, including pretreatment processes of discharge and separation, recovery of lithium, nickel, cobalt and manganese, extraction of precious metals by hydrometallurgical and pyrometallurgical processes, as well as recycling equipment, have become hotpots in this field. China has a relatively large number of core patents, mainly involving hydrometallurgical process, direct recycling process, and a combination of pyrometallurgical and hydrometallurgical processes. Finally, some countermeasures and suggestions are proposed for enhancing the competitiveness of China’s industry in recycling cathode materials in spent lithium-ion batteries, which provides references for promoting the healthy development of China’s lithium battery recycling industry.

Based on the causes of historical dam failure accidents in tailings ponds, a safety grade evaluation index system was built for tailings ponds. The correlation between safety evaluation indexes was demonstrated with Pearson correlation analysis method. An in-depth analysis was conducted for the distribution of sample data to confirm that the sample data met the requirements of the Kriging method for data distribution. Then, the weight of each safety evaluation index was calculated with entropy weight method. The two safety evaluation indexes with higher sensitivity were selected as the X-axis and Y-axis of the Kriging geostatistical model. A geostatistical model was established by using the Kriging method and was verified with empirical case data. The results show that the predicted safety grades of 12 groups of tailings pond data with known safety grades in the geostatistical model are completely consistent with the actual safety grades, which verifies the feasibility and high accuracy of this method.

Based on the mining environment and stress characteristics of backfill in the upward horizontal slicing and filling method, the influence of wetting-drying (WD) cycles on the mechanical properties of cemented tailings backfill (CTB) was explored. An ultrasonic test and a mechanical property test were conducted for CTB samples with different cement-tailings (c/t) ratios after different WD cycles to investigate variation in the velocity of longitudinal waves, compressive strength, and failure mode. The results show that after WD cycles, the CTB samples with c/t ratios of 1∶4, 1∶6 and 1∶8 all had a decreased ultrasonic wave velocity, and as the number of WD cycle increases, CTB samples with different c/t ratios had enhanced plastic deformation capacity but decreased strength. It is shown that WD cycle has a small impact on backfill with a higher c/t ratio. And the CTB without WD cycle mainly experiences tension-shear failure, while CTB after WD cycles has multiple axially parallel cracks penetrating vertically, which significantly increase after more WD cycles. It is found that the c/t ratio is a key factor for CTB to resist deterioration caused by WD cycles. In mining operation, the c/t ratio for different filling areas can be reasonably optimized to reduce filling costs.

Homogenization of backfill slurry cannot be automatically evaluated during stirring process. To solve this problem, the Yolo-v7 algorithm was improved by using the CBAM and the SPD-Conv, and the improved Yolo-v7 algorithm was then employed to automatically evaluate the homogenization of backfill slurry. The research results show that the improved Yolo-v7 algorithm demonstrates a significantly improved performance, with the accuracy, recall rate and mean average precision (mAP) all increased by 17.5, 28.8, and 32.4 percentage points respectively. Analysis of slurry parameter sensitivity indicates that slurry concentration is the principal factor affecting evaluation of slurry inhomogeneity, followed by the cement-tailings ratio. Moreover, the homogeneity of backfill slurry with high concentration can be significantly improved by prolonging stirring time.

To enhance the positioning accuracy of seismic source in underground mining and solve the problem of spatiotemporal changes in the wave velocity field caused by excavation disturbance and complex structures, seismic source relocation with real-time inversion of wave velocity field  as a prior was proposed, which combined ray tracing and quasi-Newton iteration algorithm to realize dynamic update of wave velocity field and high-precision positioning of seismic source. The validity of this method was verified by synthetic monitoring and field testing. The synthetic monitoring results showed that compared to the least squares procedure, the real-time inversion resulted in the average positioning accuracy enhanced by 49.8% and the accuracy of wave velocity inversion exceeding 95%. In the field testing, a 180 m×180 m to-be-filled area in mining operation was taken for imaging target. Compared to the least squares procedure, this method brought the average error in positioning reduced by 7.074 m, and the accuracy of wave velocity inversion in each region exceeding 95%. The research indicates that this method not only is suitable for seismic source positioning in microseismic monitoring, but also can be used as a geophysical method for detecting passive imaging of goaf areas.

The polymetallic ore from Shizhuyuan of Hunan Province was taken for research. Based on the characteristics of uneven coarse-fine dissemination of minerals and insufficient deliberation of Mo-Bi sulfide ore for flotation, an enhanced recovery technology by stepwise separation was developed for the low-grade Mo-Bi sulfide ore. The results show that an experiment by adopting such stepwise separation technique produced a bulk flotation concentrate grading 1.31% Mo and 2.83% Bi at corresponding recoveries of 88.43% and 85.99%, presenting 5.34 and 4.80 percentage points up, respectively, compared to on-site conventional bulk flotation process. This creates favorable conditions for the following tungsten flotation from the bulk flotation tailings. It is shown that a closed-circuit tungsten flotation can produce a tungsten concentrate grading 44.64% WO₃ at 84.12% recovery.

In Meishan Iron Mine, the iron concentrate produced on the site has SiO₂ grade more than 6.0%. Aiming at this problem, an experimental study was carried out based on the microscopic identification of different concentrate products by using a new process flow, in which the magnetic field intensity of low-intensity magnetic separation (LIMS) was reduced for roughing, and a process of regrinding and re-separation was added for the scavenging concentrate by high-intensity magnetic separation (HIMS). The effects of those technical transformation on the TFe grade of iron concentrate and the content of impurity SiO₂ therein were explored. The results show that after such technical transformation, the LIMS can produce a concentrate grading 63.57% TFe and 3.37% SiO₂ with corresponding recoveries of 72.79% and 12.94%, with a yield of 52.21%; while the HIMS can produce a concentrate grading 44.79% TFe and 9.07% SiO₂ with corresponding recoveries of 17.20% and 11.67%, with a yield of 17.51%. This new flowchart can produce the concentrate grading 58.85% TFe and 4.80% SiO₂ at corresponding recoveries of 89.98% and 24.61%, with a total yield of 69.72%. It is shown the SiO₂ content in the total concentrate of Meishan Mine can be greatly reduced.

Extraction of rhenium from low-grade molybdenum concentrate by adopting a process of oxidative volatilization followed by ion exchange was explored in experiments. Firstly, a two-stage high-temperature oxidative roasting was adopted to oxidize rhenium into Re₂O₇. Rhenium and molybdenum were effectively separated due to rhenium volatilizing into the flue gas. The volatilization rate of rhenium reached 85.42% after roasting process at 675 ℃. Then, the rhenium-containing flue gas was eluted to get rhenium-containing solution, in which rhenium was selectively extracted with D201×7 ion exchange resin. With the solution pH of 9, liquid/solid ratio of 50 mL/g, a 20 min adsorption at temperature of 35 ℃ brought the adsorption rate of Re up to 97.52% and the adsorption rate of Mo less than 20%. Finally, a product of ammonium rhenate was prepared by stepwise desorption followed by concentration and crystallization. By this process, the total recovery of Re can reach 70.68%.

With nickel laterite ore from Morowali of Indonesia as the raw material, effects of various factors, including reaction time and temperature, stirring speed, acid-to-ore ratio, and slurry concentration, on the leaching rate were systematically investigated. Additionally, the leaching mechanism was explored by using the PHREEQC, a thermodynamic calculation software. The results show that after one hour reaction at 250 ℃, with acid-to-ore ratio of 300 kg/t and slurry concentration of 25%, the leaching rates of Ni and Co can reach 98.40% and 99.90%, respectively, while the leaching rates of Fe and Al are just 3.84% and 40.25%, respectively. The high selectivity of high pressure acid leaching (HPAL) is attributed by the factor that at high temperatures, not only the hydrolysis reaction of Fe and Al can be promoted, but also the pOH can be decreased from 14 to 10,  which thereby inhibits leaching of Fe and Al. As the temperature rises to above 200 ℃, the number of H+ increases, which can ensure a sufficient amount of H+ for leaching of nickel and cobalt metals.

Nickel, Cobalt and Manganese in the cathode materials of spent ternary lithium-ion batteries were recovered by leaching with a combination of citric acid and hydrogen peroxide. The possible reactions during the leaching process were analyzed, and the effects of factors, including citric acid concentration, mass fraction of hydrogen peroxide, leaching temperature, leaching time and liquid-to-solid ratio on the leaching rates of nickel, cobalt and manganese from cathode materials were also investigated. It is found that after 60 min leaching at 80 ℃ with citric acid at a concentration of 1.5 mol/L, hydrogen peroxide at a mass fraction of 8%, and a liquid-to-solid  ratio of 25 mL/g, the leaching rates of nickel, cobalt and manganese are 97.58%, 97.35% and 96.12%, respectively. Then, an antisolvent crystallization method is adopted with ethanol as antisolvent agent to recover metals from the obtained leach liquor, leading to the crystallization rates of nickel, cobalt and manganese at 92.34%, 93.07% and 99.69%, respectively.

A FeCoCrNiMn high-entropy alloy (HEA) coating was prepared on the 201 stainless steel surface by adopting high-speed laser cladding technology, and then the microstructure, phase distribution, microhardness of FeCoCrNiMn coating, as well as its wear properties in dry sliding condition were all investigated. It is found that such laser cladded FeCoCrNiMn HEA coating consists of a single FCC structure, with no obvious cracks observed. It also forms a good metallurgical bond with the substrate. The microhardness of the coating is around (439±2.1)HV, nearly two times that of 201 stainless steel substrate, and the strengthening mechanisms mainly include strengthening by grain refinement and solid solution strengthening. Also, the FeCoCrNiMn coating presents an obviously better wear resistance than 201 stainless steel, with an average  friction factor of 0.246 and a specific wear rate of about 2.59×10^-6 mm³/(N·m).The wear mechanisms for it include adhesive and abrasive wear. It is concluded that such FeCoCrNiMn HEA coating prepared by high-speed laser cladding technology can significantly improve the surface hardness, wear resistance and service life of machine components.

The expanded graphite (EG) derived from the graphite anodes of spent lithium-ion batteries was taken as conductive substrate, and then Sn/Co-based bimetallic sulfide was loaded by using a hydrothermal method to synthesize SnCoS₄@EG nanocomposite. And such EG presents a cross-linked porous three-dimensional lattice, and the SnCoS4 nanocrystals in the synthesized composite are uniformly dispersed in the EG, which enhances electrical conductivity of electrode material and stability of metallic sulfide, but also increases the contact area between active sites and electrolyte, leading to a higher exchange rate of Li⁺ ions at electrode/electrolyte interface. It is shown that SnCoS₄@EG electrode can exhibit a reversible specific capacity of 1195.90 mAh/g at 1.0 A/g after 500 cycles, presenting excellent durability over a large number of cycles.

Surface mechanical attrition treatment (SMAT) was adopted for low-carbon steel materials to achieve surface nanonization, and then the influence of surface nanonization on corrosion resistance of low-carbon steel was also discussed. The results show that due to surface nanonization, the low-carbon steel has a greater plastic deformation on the surface as the carbon content decreases, and the X-ray diffraction of its surface presents obviously wider peaks. It is found that after nanosizing treatment for the surface of low-carbon steel with different carbon content, the lower the carbon content, the rougher the surface and the worse the corrosion resistance.

To investigate directional independence of multistage stress memory during progressive cyclic loading of granite under compression with a series of deflection angle, experiments were conducted on cyclic loading and unloading of granite with different deflection angles by using a self-made deflection device. The Kaiser effect (KE) and the incomplete erasion phenomenon (IEP) of the maximum stress in previous multistage cycles after progressive cyclic loading with deflection angles were explored in the experiments. Results show that both KE and IEP in granite exhibit directional independence. The directional independence of KE has a critical angle of 10° and the directional independence of IEP has a critical angle of 12°. With a deflection angle of 12°, the IEP will interfere with the memory of historical maximum stress by KE. 

In order to balance productivity against safety in the mining of high-level stope with gently-dipping and extra-thick orebody, an iron mine adopting sublevel open stoping with backfill was taken as an example to optimize the mining sequence. Firstly, pillars was determined to at a reasonable spacing from 14.2 m to 47.2 m based on the theory of bearing capacity of pillars. Secondly, according to stope structure parameters, the pillars were designed to be 15 m, 30 mand 45 m in thickness, respectively. An orebody model was also established with FLAC^3D and then was used to analyze the roof subsidence and pillar stability based on comparison of each mining scheme. Finally, a judgment matrix of mining sequence was constructed based on analytic hierarchy process and fuzzy comprehensive evaluation method, with both factors of safety and productivity taken into consideration in the numerical simulation. The comprehensive membership degrees of those three schemes were calculated to be 0.86, 0.79 and 0.80, respectively, and pillars in the best scheme were determined to be in the thickness of 15 m. The results of an industrial experiment have proven that this scheme can ensure stope with relative stability while achieving the maximum production capacity.

An iron concentrate obtained from magnetic separation of red mud from Shandong was used in an experimental study on the effect of titanium removal by reverse flotation. In the experiment, with sodium oleate as collector, corn starch as hematite depressant, sulfuric acid as pH regulator, pulp pH of 9, and the addition of corn starch and sodium oleate at an amount of 500 g/t and 1500 g/t, respectively, the iron concentrate was produced, with the TiO₂ grade fell down from 6.90% to 2.73%, and the TFe recovery reaching 41.80%. The results of collector adsorption and IR analysis show that sodium oleate exhibits selective adsorption characteristics, which has further confirmedthe feasibility of sodium oleate used in removing titanium by reverse flotation of iron concentrate obtained from magnetic separation of red mud.

An experimental research was performed on pre-enrichment of a weathered low-grade vanadium-bearing stone coal ore to solve the problems of complex flow and high cost for the existing direct vanadium-extraction process. The process mineralogy study shows that the predominant vanadium minerals in the stone coal ore are vanadium-bearing limonite and vanadium-bearing mica, both being weakly magnetic, and a superconducting magnetic separation (SMS) plus sedimentation process is proposed for pre-enrichment of vanadium. With magnetic field strength of 4 T and slurry flow rate of 8.0 L/min, SMS produced a pre-enriched concentrate with V₂O₅ grade of 1.44% at a recovery of 55.08%. The SMS tailings were then subjected to sedimentation and classification to further recover vanadium, leading to the final concentrate with V₂O₅ grade of 1.03% and recovery of 79.48%, presenting that 59.02% tailings were discarded. With this pre-enrichment process, vanadium in the stone coal ore can be efficiently reclaimed, which meets the requirements for subsequent metallurgical vanadium extraction.

The acid leaching solution of cathode materials from spent lithium iron phosphate batteries was taken as raw material, and iron, phosphorus and lithium elements therein were recovered by adopting an oxidation-precipitation process. The effects of factors, including endpoint pH value of reaction system, reaction temperature, concentration of sodium hydroxide, dripping rate of sodium hydroxide, and the volume ratio of hydrogen peroxide to acid leaching solution, on the precipitation rates of iron and phosphorus and the loss of lithium during the precipitation process were all investigated. Results show that with the endpoint pH value of 2.5, temperature of 75 ℃, sodium hydroxide with concentration of 1.5 mol/L, sodium hydroxide solution at a dripping rate of 7.7 mL/min, and hydrogen peroxide and acid leaching solution in a volume ratio of 1∶60, the average precipitation rates of iron and phosphorus are 99.86% and 98.23%, respectively, and the average loss of lithium is just 1.23%. Under the above-mentioned conditions, iron and phosphorus in the solution can be effectively removed and recycled in the form of iron phosphate, presenting a lower loss rate of lithium. After 5 h-heat treatment at 700 ℃, it is shown that the chemical composition of iron phosphate can meet the industrial standard.

Theoretical calculation was made for the flow field in the hydraulic transportation with deep-sea polymetallic nodule collector, and the relationship between particle size of polymetallic nodules and minimum conveying speed was obtained. The distribution of flow pattern in the conveying channel was simulated with the jet velocity of nozzle at 15 m/s, 20 m/s and 25 m/s respectively, and  rate of the flow at 30 mm away from the lower surface of the channel was measured. A laboratory test was conducted for nodules pick-up by using a collector with different jet velocities of nozzles, and it is found that the obtained results are consistent with the theoretical calculation and simulation results.

In order to simply and effectively evaluate slope stability, four machine learning models based on chaotic particle swarm optimization (CPSO) were proposed to solve the existing problems of algorithm selection and hyper-parameter optimization in traditional machine learning model, and their prediction performance were comprehensively compared among each other. A database consisting of 221 open-pit slope stability cases was established, in which 80% of the data were used for training and 20% for model testing. Based on the comparison between the prediction results of four models and the verification results of engineering practices, it is found that the support vector machine (SVM) based on CPSO is superior than other three machine learning models in terms of prediction of slope stability, presenting an accuracy up to 88%. Thus, it can provide a reliable prediction for the safety of slope in open-pit mine.

To utilize efficiently valuable metal resources containing lithium and beryllium, flotation experiments were conducted based on the study of ore properties. A lithium-beryllium bulk flotation process was used and the influences of dosages of regulator, activator and collector, and the stirring time of regulator on the flotation performance of lithium polymetallic ore were investigated. Based on the determined optimal dosages of calcium chloride and collectors of GYLZ and GYM3, a closed-circuit test produced a lithium concentrate with Li₂O grade and recovery of 6.10% and 94.01% respective, and BeO grade and recovery of 0.12% and 88.53%, respectively, achieving efficient recovery and utilization of lithium and beryllium resources in lithium polymetallic ores.

The occurrence state of iron minerals in a kind of kaolin ore in Guangdong is relatively complex. A portion of iron minerals is irremovable as they disseminate in the lattice of kaolinite, illite and other minerals in an isomorphic manner. For this reason, the calcined kaolin concentrate possesses a lower whiteness than the natural whiteness. In order to efficiently exploit and utilize the kaolin ore, a process consisting of slurry tamping, spiral classifier classification and hydrocyclone classification was adopted, resulting in a kaolin concentrate grading 30.02% Al₂O₃ at 61.70% recovery with the content of impurity Fe₂O₃ at 1.15%, which can reach grade III standard of kaolin for ceramic industry. The classification downflow was then subjected to a process consisting of grinding, magnetic separation and hydrocyclone classification, resulting in a quartz sand concentrate and a sericite concentrate. The quartz sand concentrate, containing 97.11% SiO₂ and 0.058% Fe₂O₃, can satisfy the standard for low quality quartz for glass industry, and the sericite concentrate, containing 7.07% K₂O, 31.22% Al₂O₃ and 48.32% SiO₂, with natural whiteness at 65.53%, can be used in the coating industry. The magnetic separation results in the tailings with a yield of 8.41% and SiO₂ content of 76.33%, which can be used as auxiliary materials for building sand. Through this process, different minerals can be effectively separated to achieve the purpose of comprehensive utilization of kaolin ore.

To examine the industrial feasibility of pre-discarding by using screening classification combined with gravity separation in processing of a scheelite ore from Hunan Province, industrial distributary and flotation trial tests were carried out. The results show that a process consisting of  screening and spiral chute discarding  under optimized conditions can discard tailings grading 0.034% WO₃ with a yield of 25.50% in mass, leading to tungsten loss of only 2.99%. With this pre-discarding before flotation process, both the grade and recovery of the final flotation concentrate are improved, compared to the concentrate obtained from direct flotation of overflow product.

In order to recover and utilize high value-added iron phosphate waste, an experimental study was carried out by adopting a process consisting of hydrochloric acid leaching, replacement of iron powder for copper removal, and hydrolyzation and chemical precipitation for removal of titanium and aluminum therein. The results show that after 1 h leaching at 60 ℃ with hydrochloric acid concentration of 25%, liquid-solid ratio of 6 mL/g, the leaching rate of iron can be up to 98.7%. And then after 35 min reaction at 60 ℃ with the initial pH of the solution controlled at 0.6, the addition of iron powder at an amount of 0.55 times of the molar number of iron in the leaching solution, the removal rate of copper and titanium can reach 96.2% and 83.6% respectively. By the following process of hydrolyzation and chemical precipitation with sodium fluoride 8 times of the molar number of aluminum, the removal rate of titanium and aluminum can reach 97.6% and 99.3% after 30 min reaction at 40 ℃ with pH of 1.9. It is shown that the content of impurities in the leaching solution meets the requirements for the subsequent synthesis of iron phosphate for batteries.

A kind of contaminated paddy soil was taken for pot experiment by adding FeSO₄ to investigate the impact of FeSO₄ on the formation of iron plaques on the root surface and the migration of the Cd from Cd-contaminated paddy soil. Results show that with the addition of FeSO₄ increased from 0 to 320 mg/kg, the pH value of the paddy soil tends to decline, maximally by 0.70. The TCLP-Cd content in the potting soil rises to a certain extent compared to the control group. The addition of FeSO₄ significantly reduces the Cd content in leaves, husks, and brown rice, as well as effectively increases the amount of root iron plaque, thus the absorption of Cd in the soil by rice is moderately controlled. However, the addition of external iron resource can bring impact to the pH of soil and bioavailability of Cd, so it is recommended that in practical operation, FeSO₄ should be added with some alkaline restorative materials such as lime to contaminated paddy fields for enhancing the control.

Methylene blue was degraded by adopting a heterogeneous Fenton system composed of manganese residue and H₂O₂, and the effects of initial pH value, H₂O₂ concentration, dosage of manganese residue and reaction temperature on the degradation performance were studied. The reusability of manganese residue was investigated, and the removal mechanism of methylene blue in the manganese residue/H₂O₂ system was also discussed. The results show that the removal rate of methylene blue can exceed 98.1% after 120 min reaction at temperature of 25 ℃, with methylene blue concentration of 20 mg/L, H₂O₂ concentration of 10 mmol/L, manganese residue dosage of 2 g/L, and initial pH value of 2.5. After the manganese residue is recycled for 5 times, the removal rate of methylene blue can be still up to 95.5% by 300 min reaction. In the manganese residue/H₂O₂ heterogeneous Fenton system, ·OH plays a leading role in the degradation of methylene blue.

With micron silicon powder as matrix, phosphorus-doped silicon-carbon composite material (Si-P@C) was synthesized by solid-state thermal diffusion and high-temperature pyrolysis, and then used as anode material of lithium-ion batteries. The results show that Si-P@C anode material demonstrates an initial discharge specific capacity up to 2 164 mAh/g  at a current density of 0.2 A/g. Compared with pure silicon, Si-P@C anode material presents greatly improved cycling performance. After 50 cycles at a current density of 0.5 A/g, it demonstrates a high reversible specific capacity of 1 176 mAh/g, with the capacity retention ratio of 73.5%. It is concluded that phosphorus-doping and carbon coating can effectively improve the electron transfer ability and reaction kinetics of silicon anode.

To solve the problem of structural instability of cathode material (LiNi_0.8Co_0.1Mn_0.1O₂) (NCM)) during cycling, a strategy of  co-doping of Rb⁺ and Cl^- was proposed for NCM materials. The synergistic effect of  co-doping of Rb⁺ and Cl^- in the NCM lattice can increase the diffusion rate of Li⁺ and relieve the internal strain, thus hindering the mixing of Li⁺/Ni²⁺ during high cut-off voltage cycling. Electrochemical test results show that Li_0.99Rb_0.01(Ni_0.8Co_0.1Mn_0.1)O_1.99Cl_0.01 (RbCl-NCM) has a discharge capacity up to 176.9 mAh/g at a current density of 10C. The initial discharge capacity at  1C is 203.5 mAh/g.  After 200 cycles, its capacity retention ratio is as high as 87.8%,  showing an excellent cycling performance, while the capacity retention ratio of NCM material is only 57.3%.

The comprehensive recycling ways for tailings after vanadium extraction, including recovery of valuable components, synthesis of new functional materials and preparation of multi-purpose building materials, were explained, which can provide a reference for application of technologies in comprehensive recycling of tailings after vanadium extraction.

Based on the experimental study on fragmentation and pulverization characteristics of polymetallic nodules in the process of ore lifting, it is found that there is obvious fragmentation of nodules during lifting process. With the volume concentration of 6.5%, the mass percent of polymetallic nodules with particle size larger than 50 mm decreases from 75.58% to 23.78%; with the volume concentration of 15%, the mass percent decreases from 51.51% to 10.08%.Pulverization of nodules was observed in the experiment. With the volume concentration of 6.5%, the mass percent of the polymetallic nodules powder with particle size less than 0.1 mm is 1.79%, and the median particle size is 10.07 μm; with the volume concentration of 15%, the mass percent of polymetallic nodule powder with particle size less than 0.1 mm is 1.99%, and the median particle size of the powder is 9.47 μm. Based on the experimental data, it is estimated that as per mining of 10 million tons of polymetallic nodules, the powder discharge will cause tens of thousands of tons of Fe and Mn losses, as well as hundreds of tons of Co, Ni and Cu losses. Besides, the maximum redeposition thickness of the sediment plume induced by mining is more than 3 mm after diffusion and settlement, which will bring a significant impact to environment.

The stability of slope with fault under the impact of  blast-induced seismic wave was analyzed by using simulation to study the dynamic response of slope with different fault thickness under the impact of explosive vibration. The results show that there exists elevation amplification effect when blast-induced seismic wave propagates along slope surface and fault area. The thicker the fault, the faster the attenuation of blast-induced seismic wave. As the fault becomes thicker, the displacement of slope under the action of blast-induced vibration gradually increases, and the overall deformation resistance becomes smaller. Under the action of blast vibration, the fault with different thickness obviously brings different influence to slope stability. With the fault thickness of 2-8 m, the slope stability decreases continuously and rapidly, and tends to be stable as the fault thickness exceeds 8 m.

The single application of analytical hierarchy process (AHP) and grey relational analysis (GRA) algorithm is always affected by some subjective factors, leading to great deviation between the obtained evaluation result and the actual result. In view of this problem, a composite algorithm based on an integrated range analysis with GRA and AHP was proposed. Then, a phosphate mine in the southwest China was taken as an example, and this algorithm was adopted  to analyze the sensitivity of factors, including gravity, internal friction angle, cohesive force, elastic modulus and Poisson'sratio, to the stability of slope in the Area A. The results show that the sensitivity of those influencing factors to the slope stability in Area A is in the following descending order: internal friction angle, cohesive force, gravity, elastic modulus, Poisson's ratio. It is found that the analysis result is consistent with the actual situation of the mine.

Mineral processing tests were carried out for a low-grade copper ore from South America containing 0.027% Mo and 0.45% Cu. After optimization of the reagent regime, a close-circuit test by adopting a flowsheet of Cu-Mo bulk flotation plus Cu/Mo separation resulted in a copper concentrate grading 26.93% Cu at 81.96% recovery, and a molybdenum concentrate grading 25.32% Mo at 76.24% recovery. Therewith, copper and molybdenum resources in the lean ore can be effectively recovered.

The kinetics and thermodynamics of oleate ion adsorption on the surface of fluorapatite and dolomite were studied by adopting TOC measurement and molecular simulation. The study on kinetics of adsorption shows that with HEDP as the depressant, the adsorption rate of oleate ions on fluorapatite is greater than on dolomite, and the adsorption on both minerals conforms to the quasi-second-order kinetic model. Furthermore, according to the study on adsorption thermodynamics, the characteristics of oleate ion adsorption on the inner pore surface of both fluorapatite and dolomite, on (001) surface of fluorapatite and (104) surface of dolomite nearly conform to Langmuir model. For identical specific surface area, the adsorption amount of oleate ions on dolomite is higher than that on fluorapatite, indicating that there are more active sites per unit surface area on dolomite than on fluorapatite.

The crystal structure and surface properties of minerals and the mechanism of interaction between minerals and flotation agents were systematically analyzed by means of quantum chemical calculation and molecular dynamics simulation. Meanwhile, the flotation mechanism of kyanite minerals and quartz was discussed. The results show that the differences in the surface properties of kyanite, andalusite, sillimanite and quartz determine the differences in floatability, and citric acid can increase the floatability difference between kyanite minerals and quartz. The simulation result of computational chemistry  is consistent with the experimental result of flotation.

With orange residue extract and tetrasodium glutamate diacetate (GLDA) as raw materials, a green activator was prepared. Then, the effects of phosphate-solubilizing bacteria (PSB) combined with green activator on the enrichment, translocation and accumulation of cadmium from soil by ryegrass were studied. The results show that PSB can significantly promote the growth of ryegrass in cadmium-contaminated soil. However, the growth of ryegrass is inhibited by only using green activator, with the dry weight of ryegrass at the end of experiment decreased by 27.37%; while a combination of PSB and green activator can make the final dry weight of ryegrass become 1.29 times that in the blank group, indicating that the addition of PSB can alleviate the negative effect of green activator on the growth of ryegrass. A combination of both can increase the content of phytoavailable cadmium in soil, while decrease the total cadmium concentration in soil. It is shown that the enrichment coefficient of Cd in stem and root parts of ryegrass increases by 35.37% and 10.23%, respectively, and the translocation factor of cadmium by ryegrass increases by 22.58%. In addition, the total accumulation of cadmium in the stem and root parts of ryegrass is up by 87.90% and 32.69%, respectively. It is found that the total accumulation of cadmium in the stem is all greater than that in the root whether by using PSB and green activator separately, or by a combination of both, indicating that PSB combined with green activator can promote the phytoextraction efficiency of cadmium from soil by ryegrass.

Acting as a raw material, mangosteen peel  was subjected to decolorization with isopropanol and activation with alkaline reagent for preparing a kind of adsorbent, which was then used to adsorb copper ions in solution. The result from an adsorption experiment shows that increasing pH value can be beneficial to the adsorption of copper ions onto mangosteen peel, with the maximum adsorption capacity up to 1.5 molCu²⁺/kg. The adsorption can reach equilibrium within 30 min. The amount of loaded copper ions has a significant effect on the characteristic temperature of thermal decomposition of adsorbents during combustion. When the concentration of copper ions is lower than 2 mmol/L, there are higher number of loaded copper ions, and the temperature at which thermal decomposition begins and violent combustion decomposition ends becomes lower. When the concentration of copper ion is higher than 2 mmol/L, the characteristic value of thermal decomposition temperature no longer changes significantly. Copper ion plays a role of catalyst in the combustion process, which can effectively promote the combustion reaction.

A side blowing furnace was adopted to treat the leaching residue of copper anode slime and recover valuable metals therein comprehensively. The effects of soda dosage, granular coal dosage, precipitation time and top flue gas temperature on the recovery rates of main metals Pb, Sb, Bi, Au and Ag were investigated. The results show that with soda at an amount of 2.5%, granular coal at an amount of 3%, the precipitation time of 1.5 h, and the top flue gas temperature of 750 ℃, the precious lead product is obtained after processing, grading 1 544 g/t Au (1.84 times enrichment), 10.37% Ag (1.4 times enrichment), 22.89% Pb (2.1 times enrichment), and 27.45% Bi (2.2 times enrichment).